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Magnetic Properties of Hexanuclear Lanthanide(III) Clusters Incorporating a Central μ<sub>6</sub>-Carbonate Ligand Derived from Atmospheric CO<sub>2</sub> Fixation

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NIAID Data Ecosystem2026-03-07 收录
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Three isostructural hexanuclear lanthanide­(III) clusters are reported (LnIII = Gd, Tb, and Dy). The metallic core of each complex displays an unusual arrangement of ions, which is stabilized by a μ6-carbonate ligand. Magnetic studies show that the LnIII ions in each compound are weakly exchange coupled, with the Tb and Dy analogues displaying single-molecule-magnet behavior.

创建时间:
2012-04-02
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