Structurally Defined α‑Tetralol-Based Chiral Hypervalent Iodine Reagents
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下载链接:
https://figshare.com/articles/dataset/Structurally_Defined_Tetralol-Based_Chiral_Hypervalent_Iodine_Reagents/8309381
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资源简介:
A novel
class of chiral hypervalent iodine reagents containing
an α-tetralol scaffold is introduced. Iodine triacetate is employed
in a key step as a highly selective and efficient iodinating reagent
for a short and convenient synthesis of iodine(III) derivatives. Solid-state
X-ray analyses offer valuable structural information, while reactivities
and stereoselectivities are investigated in three model reactions.
创建时间:
2019-06-09



