Iron-Catalyzed, Chelation-Induced Remote C–H Allylation of Quinolines via 8‑Amido Assistance
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https://figshare.com/articles/dataset/Iron_Catalyzed_Chelation_Induced_Remote_C_H_Allylation_of_Quinolines_via_8_Amido_Assistance/2273245
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An iron-catalyzed, 8-amido-enabled regiodivergent C–H allylation of quinolines is described. This reaction represents a rare example of chelation-induced geometrically inaccessible C–H functionalization, allowing for the highly regio- and stereoselective preparation of either the C5- or the C4-allylated quinoline scaffolds regiocontrolled by the catalytic systems.
创建时间:
2016-02-17



