Kinetic Control of Rh(III)-Catalyzed Annulation of C–H Bonds with Quinones: Chemoselective Synthesis of Hydrophenanthridinones and Phenanthridinones
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https://figshare.com/articles/dataset/Kinetic_Control_of_Rh_III_Catalyzed_Annulation_of_C_H_Bonds_with_Quinones_Chemoselective_Synthesis_of_Hydrophenanthridinones_and_Phenanthridinones/2074045
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资源简介：
A temperature-dependent redox-neutral
Rh(III)-catalyzed C–H
bond annulation of N-methoxybenzamides with quinones
was developed for the chemoselective synthesis of hydrophenanthridinones
and phenanthridinones. This reaction involves an Rh(III)-catalyzed
C–H bond functionalization and a subsequent cyclization through
the directing group nucleophilic addition to the carbonyl group at
room temperature.
创建时间：
2016-02-12
