Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands
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Novel molybdenum– and tungsten–dinitrogen complexes bearing PNP-type pincer ligands are prepared and characterized by X-ray analysis. Reactions of these molybdenum– and tungsten–dinitrogen complexes with an excess amount of sulfuric acid in THF at room temperature afford ammonia and hydrazine in good yields.
创建时间:
2016-02-21



