Anionic Halide···Alcohol Clusters in the Solid State
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https://figshare.com/articles/dataset/Anionic_Halide_Alcohol_Clusters_in_the_Solid_State/2246899
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资源简介：
The cationic (1,3,5-triazapentadiene)PtII complexes
[1](Cl)2, [2](Cl)2, [3](Br)2, and [4](Cl)2, were crystallized from ROH-containing systems (R = Me, Et)
providing alcohol solvates studied by X-ray diffraction. In the crystal
structures of [1–4][(Hal)2(ROH)2] (R = Me, Et), the Hal– ion interacts
with two or three cations [1–4]2+ by means of two or three or four contacts thus uniting stacked
arrays of complexes into the layers. The solvated MeOH or EtOH molecules
occupy vacant space, giving contacts with [1–4]2+, and connects to the Hal– ion through a hydrogen bridge via the H(1O)O(1S) H atom forming,
by means of the Hal–···HOR (Hal =
Cl, Br) contact, the halide–alcohol cluster. Properties of
the Cl–···HO(Me) H-bond in [1][(Cl)2(MeOH)2] were analyzed using
theoretical DFT methods.
创建时间：
2014-10-09
