Synthesis and Chiroptical Properties of a Ring-Fused BODIPY with a Skewed Chiral π Skeleton
收藏NIAID Data Ecosystem2026-03-09 收录
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A twisted chiral boron–dipyrrin complex (BODIPY) was synthesized by oxidative annulation of the biphenyl units at the β positions. The chiral BODIPY has two asymmetric carbons in the large planar skeleton, which were generated upon the ring-fused reaction. Its π-elongated and twisted structure resulted in the Cotton effect in the red region (λmax = 614 nm, Δε = 60 M–1·cm–1) as well as the strong fluorescence (ΦF = 0.73) and circularly polarized luminescence (CPL).
创建时间：
2016-05-27
