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Enantioselective Aza-Heck Cyclizations of N‑(Tosyloxy)carbamates: Synthesis of Pyrrolidines and Piperidines

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Figshare2019-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Enantioselective_Aza-Heck_Cyclizations_of_i_N_i_Tosyloxy_carbamates_Synthesis_of_Pyrrolidines_and_Piperidines/7730528
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资源简介:
Pd­(0)-systems modified with SPINOL-derived phosphoramidate ligands promote highly enantioselective aza-Heck cyclizations of alkenyl N-(tosyloxy)­carbamates. The method provides versatile access to challenging N-heterocycles and represents the broadest scope enantioselective aza-Heck protocol developed to date.
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2019-02-17
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