A Cyanide-Bridged Molybdenum Bis(maleonitriledithiolate) Square
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https://figshare.com/articles/dataset/A_Cyanide_Bridged_Molybdenum_Bis_maleonitriledithiolate_Square/2335573
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资源简介：
[Et4N]2[MoIVO(mnt)2] (mnt = maleonitriledithiolate)
reacts, as a synthon, with Me3SiCN under an acidic medium
to produce the square complex [Et4N]4[Mo4(μ-CN)4(mnt)8] (1) in high yield. Complex 1 shows strong antiferromagnetic
interactions between adjacent Mo atoms in the cluster. The presence
of redox-active mnt as a capping ligand strongly influences the magnetic
property of 1. The physicochemical properties of 1 have been rationalized by density functional theory level
of calculations.
创建时间：
2016-02-18
