Aryne 1,2,3-Trifunctionalization with Aryl Allyl Sulfoxides
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https://figshare.com/articles/dataset/Aryne_1_2_3-Trifunctionalization_with_Aryl_Allyl_Sulfoxides/3643353
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资源简介：
An
aryne 1,2,3-trisubstitution with aryl allyl sulfoxides is accomplished,
featuring an incorporation of C–S, C–O, and C–C
bonds on the consecutive positions of a benzene ring. The reaction
condition is mild with broad substrate scope. Preliminary mechanistic
study suggests a cascade formal [2 + 2] reaction of aryne with SO
bond, an allyl S → O migration, and a Claisen rearrangement.
创建时间：
2016-08-26
