Alkenylation of Phosphacoumarins via Aerobic Oxidative Heck Reactions and Their Synthetic Application to Fluorescent Benzophosphacoumarins
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https://figshare.com/articles/dataset/Alkenylation_of_Phosphacoumarins_via_Aerobic_Oxidative_Heck_Reactions_and_Their_Synthetic_Application_to_Fluorescent_Benzo_phospha_coumarins/2194240
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资源简介:
Alkenylation of phosphacoumarins
is developed from the reaction
of phosphacoumarins with a variety of activated as well as nonactivated
alkenes via aerobic oxidative Heck reactions. In addition, 3-alkenylphosphacoumarins
undergo an inverse electron demand Diels–Alder reaction (IEDDA)
with enamines in situ generated from ketone and pyrrolidine
followed by 1,2-elimination and a dehydrogenation, producing fluorescent
benzophosphacoumarins.
创建时间:
2016-02-14



