Enantioselective Haloetherification by Asymmetric Opening of meso-Halonium Ions
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Enantioselective_Haloetherification_by_Asymmetric_Opening_of_i_meso_i_Halonium_Ions/2686720
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A new approach to enantioselective haloetherification reactions via desymmetrization of in situ-generated meso-halonium ions is described. The combination of N-haloamides as a halogen source and sodium salts of chiral phosphoric acids as catalysts can be used for the cyclization of symmetrical ene-diol substrates, yielding the haloetherification products under practical conditions in enantioenriched form.
创建时间：
2016-02-23
