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Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols

NIAID Data Ecosystem2026-03-06 收录

数据链接：

https://figshare.com/articles/dataset/Gold_I_Catalyzed_Enantioselective_Ring_Expansion_of_Allenylcyclopropanols/2844907 数据链接链接失效反馈

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资源简介：

Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols

应用场景：

创建时间：

2009-07-08

有机合成方法

羰基化反应

A simple method for accessing perfluoroalkyl-substituted enones is described applying a four-component palladium-catalyzed carbonylative coupling of aryl boronic acids together with terminal alkynes a

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Aza-Morita−Baylis−Hillman Reactions and Cyclizations of Conjugated Dienes Activated by Sulfone, Ester, and Keto Groups

有机合成方法

哌啶与嘧啶衍生物合成

The aza-Morita−Baylis−Hillman reactions of aldimines 2 with several activated conjugated dienes were found to proceed smoothly in DMF in the presence of 3-hydroxyquinuclidine (HQD). Imines 2 reacted w

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Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes

有机合成方法

环戊二烯

By treatment with LiAlH4, 1,4-dicyano-1,4-bis(trimethylsilyl)-1,3-dienes underwent a novel hydride-induced nucleophilic intermolecular 1,4-addition to the α,β-unsaturated nitrile moiety, followed by a

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Synthesis of (±)-Idarubicinone via Global Functionalization of Tetracene

药物合成

有机合成方法

Anthracyclines are archetypal representatives of the tetracyclic type II polyketide natural products that are widely used in cancer chemotherapy. Although the synthesis of this class of compounds has

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Enantiopure 2-Substituted Glyceraldehyde Derivatives by Aza-Claisen Rearrangement or C-Alkylation of Enamines

手性合成

不对称催化

2-Alkyl derivatives of butane-2,3-diacetal (BDA) protected glyceraldehyde were stereoselectively prepared by aza-Claisen rearrangement of N-allyl-enammonium ions or C-alkylation of enamines. This allo

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Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols

资源简介：

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