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This is the experimental data of the manuscript entitled “A novel collaborative electric vehicle routing problem with multiple prioritized time windows and time-dependent hybrid recharging”. In these instances,the number of depots is set to 3, 4, and 5, and the number of customers is set to 50, 75, 100, and 125 respectively. In these instances, the number of recharging stations varies from 2 to 6, and customer demand ranged from 10 to 40. The name of each instance is composed of a combination of {type} {quantity} for customers, depots, and recharging stations. For example, the instance "C50_D3_R2" means that the delivery system includes 50 customers, 3 depots, and 2 recharging stations.