Palladium-Catalyzed Carbene Migratory Insertion and Trapping with Sulfinic Acid Salts toward Allylic Sulfones
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https://figshare.com/articles/dataset/Palladium-Catalyzed_Carbene_Migratory_Insertion_and_Trapping_with_Sulfinic_Acid_Salts_toward_Allylic_Sulfones/6118466
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资源简介：
Allylic
sulfones were synthesized with excellent selectivity and
good yield via Pd-catalyzed cross-coupling of vinyl iodide with N-tosylhydrazone. This process involves palladium carbene
migratory insertion/trapping with sulfinic acid salts. For
the previous Pd-catalyzed N-tosylhydrazone cross-coupling,
sulfinic acid salt is generated as a byproduct. In this transformation,
the diazo compound and the sulfinic acid salt, which are all generated
from N-tosylhydrazone, were used as cross-coupling
partner.
创建时间：
2018-04-09
