Reactions of Zirconocene Butadiyne or Monoyne Complexes with Nitriles: Straightfoward Synthesis of Functionalized Pyrimidines
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Reactions_of_Zirconocene_Butadiyne_or_Monoyne_Complexes_with_Nitriles_Straightfoward_Synthesis_of_Functionalized_Pyrimidines/2367151
下载链接
链接失效反馈官方服务：
资源简介：
Zirconium-mediated
multicomponent reactions of silyl-butadiynes
with two molecules of aryl nitriles are described, which provide rapid
access to polysubstituted pyrimidines in a regioselective manner and
in one pot. Employing aliphatic nitriles results in coupling of only
one nitrile, leading to the formation of enynyl ketones after hydrolysis.
A zirconocene monoyne complex undergoes similar reactions with nitriles
to form highly substituted pyrimidines.
创建时间：
2013-10-14
