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A Robust, Air-Stable, Reusable Ruthenium Catalyst for Dehydrogenation of Ammonia Borane

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Robust_Air_Stable_Reusable_Ruthenium_Catalyst_for_Dehydrogenation_of_Ammonia_Borane/2614612
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We describe an efficient homogeneous ruthenium catalyst for the dehydrogenation of ammonia borane (AB). This catalyst liberates more than 2 equiv of H2 and up to 4.6 system wt % H2 from concentrated AB suspensions under air. Importantly, this catalyst is robust, delivering several cycles of dehydrogenation at high [AB] without loss of catalytic activity, even with exposure to air and water.
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2016-02-23
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