Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_a_Transient_Terminal_Nitrido_Complex_of_Rhodium/2349130
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资源简介：
Irradiation
of rhodium(II) azido complex [Rh(N3){N(CHCHPtBu2)2}] allowed for the spectroscopic
characterization of the first reported rhodium complex with a terminal
nitrido ligand. DFT computations reveal that the unpaired electron
of rhodium(IV) nitride complex [Rh(N){N(CHCHPtBu2)2}] is located in an antibonding Rh–N π*
bond involving the nitrido moiety, thus resulting in predominant N-radical
character, in turn providing a rationale for its transient nature
and observed nitride coupling to dinitrogen.
创建时间：
2016-02-18
