Copper(I)-Catalyzed Kinetic Resolution of <i>N</i>‑Sulfonylaziridines with Indoles: Efficient Construction of Pyrroloindolines
收藏NIAID Data Ecosystem2026-03-08 收录
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The first Lewis acid catalyzed [3 + 2] annulation of indoles and 2-aryl-N-tosylaziridines was realized by using copper(I)/chiral diphosphine complexes as a catalyst. With this method, a variety of uniquely substituted chiral pyrroloindolines bearing multiple contiguous stereogenic centers were facilely accessed in a straightforward, high-yielding, and highly stereoselective way under mild conditions.
创建时间：
2016-02-13
