Synergistic Cu2 Catalysts for Formic Acid Dehydrogenation
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https://figshare.com/articles/dataset/Synergistic_Cu_sub_2_sub_Catalysts_for_Formic_Acid_Dehydrogenation/8156381
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Hexanuclear copper hydride complexes, [Cu6(μ3-H)2(meso-L4)3(RNC)4](PF6)4 (R = tBu (6a), Cy (6b)), were prepared by using a new linear tetraphosphine, meso-Ph2PCH2P(Ph)(CH2)4P(Ph)CH2PPh2 (meso-L4), and were converted into active catalysts of [Cu2(μ-O2CH)(meso-L4)(RNC)2]+ under the reaction conditions of formic acid dehydrogenation, where unsymmetric dinuclear copper sites supported by the tetradentate phosphine and isocyanide ligands were essential to demonstrate effective catalytic activity.
创建时间：
2019-05-14
