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Reactivity of Bis(silyl)platinum(II) Complexes toward Organic Isothiocyanates: Preparation and Structures of (Dithiocarbonimidato)- and (Diphenylsilanedithiolato)platinum(II) Complexes, <i>cis</i>-[Pt(S<sub>2</sub>CNPh)L<sub>2</sub>] and <i>cis</i>-[Pt(S<sub>2</sub>SiPh<sub>2</sub>)L<sub>2</sub>] (L = PMe<sub>2</sub>Ph, PEt<sub>3</sub>; L-L = dppp)

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Reactions of the bis(silyl)platinum(II) complexes [Pt(SiHPh2)2L2] (L = PMe3, PMe2Ph, PEt3; L-L = dppp (1,3-bis(diphenylphosphino)propane)) with organic isothiocyanates (RNCS) produced the dithiocarbonimidato complexes [Pt(S2CNR)L2] (R = Ph, p-tolyl, 2,6-Me2C6H3, i-Pr) or the diphenylsilanedithiolato complexes [Pt(S2SiPh2)L2], depending on the reaction temperature, the stoichiometry, and the nature of the phosphine ligand.

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2016-02-27
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