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Synthesis and Characterization of Isodiphenylfluorindone and Isodiphenylfluorindinone

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Isodiphenylfluorindone_and_Isodiphenylfluorindinone/6103763
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Isodiphenylfluorindone 6 and isodiphenylfluorindinone 7 are synthesized. The former reacts with NaOMe to give the 13-methoxyisodiphenylfluorindone 22 (95%), while the latter reacts with 70% perchloric acid to give the bisperchlorate 21 (87%) and with MnO2 dimerizes to give 13,13′-bi­(isodiphenylfluorindone) 4 (60%). UV–vis, NMR, CV, and DFT computational studies support the structural assignments of all products. Single-crystal X-ray diffraction studies are reported for isodiphenylfluorindinone 7.
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2018-04-05
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