Synthesis and Characterization of Isodiphenylfluorindone and Isodiphenylfluorindinone
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Isodiphenylfluorindone_and_Isodiphenylfluorindinone/6103763
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Isodiphenylfluorindone 6 and isodiphenylfluorindinone 7 are synthesized. The
former reacts with NaOMe to give the
13-methoxyisodiphenylfluorindone 22 (95%), while the
latter reacts with 70% perchloric acid to give the bisperchlorate 21 (87%) and with MnO2 dimerizes to give 13,13′-bi(isodiphenylfluorindone) 4 (60%).
UV–vis, NMR, CV, and DFT computational studies support the
structural assignments of all products. Single-crystal X-ray diffraction
studies are reported for isodiphenylfluorindinone 7.
创建时间:
2018-04-05



