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A Concise Approach to a Gelsemine Core Structure using an Oxygen to Carbon Bridge Swapping Strategy

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https://figshare.com/articles/dataset/A_Concise_Approach_to_a_Gelsemine_Core_Structure_using_an_Oxygen_to_Carbon_Bridge_Swapping_Strategy/2902456
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A tricyclic core structure 2 related to gelsemine 1 was synthesized from an oxabicyclo[3.2.1]octanone 4 by a three-step bridge swapping strategy involving elimination of the bridging ether oxygen and intramolecular Michael addition of a tethered cyanoacetamide unit.
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2016-02-27
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