Total Synthesis of Aplykurodinone‑1
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https://figshare.com/articles/dataset/Total_Synthesis_of_Aplykurodinone_1/2257822
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资源简介：
The
concise total synthesis of aplykurodinone-1 with an unusual cis-fused hydrindane moiety has been accomplished without
the need for any protecting group chemistry using a unique SmI2 mediated reductive cascade cyclization reaction and a direct
cuprate mediated 1,4-addition. This work represents the first example
of the use of a SmI2-mediated intramolecular cascade cyclization
reaction between “halide, alkene and aldehyde” groups.
创建时间：
2016-02-16
