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Sequential σ‑Bond Insertion/Benzannulation Involving Arynes: Selective Synthesis of Polysubstituted Naphthalenes

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https://figshare.com/articles/dataset/Sequential_Bond_Insertion_Benzannulation_Involving_Arynes_Selective_Synthesis_of_Polysubstituted_Naphthalenes/6608138
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An interesting σ-bond insertion/benzannulation reaction for the synthesis of polysubstituted naphthalene derivatives has been developed from readily accessible ketones, arynes, and alkynoates. This practical and transition-metal-free method provides a novel route to diverse naphthalenes through a substrate-controlled rearrangement reaction with the cleavage of C–C bonds.
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2018-06-19
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