Novel Intramolecular Photocyclization of α-Arylthiophene Derivatives
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https://figshare.com/articles/dataset/Novel_Intramolecular_Photocyclization_of_Arylthiophene_Derivatives/2539825
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资源简介:
Photoirradiation of α-arylthiophene derivatives linked with an alkene moiety through a three-atom spacer gave unprecedented cyclobutene-fused perhydrothiapentalene-type compounds in high yields, but neither [2 + 2] nor [4 + 2] cycloaddition products. The reaction afforded a single diastereomer in many cases. The chemical structure and relative configuration of a typical product were unambiguously determined by X-ray crystallographic analysis.
创建时间:
2012-03-16



