New Boron-Containing Molybdenum Imido Alkylidene Complexes for Linear Olefin Homometathesis
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/New_Boron_Containing_Molybdenum_Imido_Alkylidene_Complexes_for_Linear_Olefin_Homometathesis/2366956
下载链接
链接失效反馈官方服务：
资源简介：
The new molybdenum imido alkylidene
complex Mo(N(2,6-iPr2C6H3))(CHCMe2Ph)(NC4H2Me2)(OB(Mes)2) (1; Mes =
2,4,6-MePh) containing both boroxide and pyrrolide
ligands is reported. Its formation results from the reaction between
bis(mesityl)borinic acid ((Mes)2BOH) and the bis-pyrrolide
Schrock-type precursor Mo(N-2,6-iPr2C6H3)(CHCMe2Ph)(NC4H2Me2)2. The complex was fully characterized
by 1H, 13C, 11B, and 95Mo NMR spectroscopy, X-ray diffraction, and elemental analysis. Complex 1 proved to be active for homometathesis reactions of 1- and
2-octene at 0.1 mol % loading. The synthesis of mixed pyrrolide boroxide
imido molybdenum alkylidene complexes was extended to other borinic
acids. The catalytic activity of these new complexes was evaluated
in the homometathesis of linear olefins.
创建时间：
2013-10-14
