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NaCl-Type Frameworks of [M(pyrazine)<sub>2</sub>NO<sub>2</sub>]ClO<sub>4</sub> (M = Co, Cu), the First Examples Containing μ<sub>1,3</sub>-Nitrito Bridges Showing Antiferromagnetism

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Two new 3D NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), consist of (4, 4) sheets of metal−pyrazine connected by μ1,3-nitrito, representing the first examples of μ1,3-nitrito bridges and exhibiting antiferromagnetism.

创建时间:
2006-11-13
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