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A Synthesis of the Carbocyclic Core of Maoecrystal V

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https://figshare.com/articles/dataset/A_Synthesis_of_the_Carbocyclic_Core_of_Maoecrystal_V/2756236
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An approach toward the synthesis of the complex polycyclic diterpene maoecrystal V (1) is described. Construction of the advanced tetracyclic core structure (i.e., 19) was achieved in 13 steps from 3,3-dimethylcyclohexanone (6) by employing a stereoselective Nazarov cyclization followed by a Diels−Alder reaction to forge the two contiguous quaternary stereocenters.
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2010-07-02
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