A Synthesis of the Carbocyclic Core of Maoecrystal V
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资源简介：
An approach toward the synthesis of the complex polycyclic diterpene maoecrystal V (1) is described. Construction of the advanced tetracyclic core structure (i.e., 19) was achieved in 13 steps from 3,3-dimethylcyclohexanone (6) by employing a stereoselective Nazarov cyclization followed by a Diels−Alder reaction to forge the two contiguous quaternary stereocenters.
创建时间：
2010-07-02
