Investigations into an Anionic Oxy-Cope/Transannular Conjugate Addition Approach to 7,20-Diisocyanoadociane
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https://figshare.com/articles/dataset/Investigations_into_an_Anionic_Oxy_Cope_Transannular_Conjugate_Addition_Approach_to_7_20_Diisocyanoadociane/2257801
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资源简介：
An
anionic oxy-Cope/transannular conjugate addition approach to
the potent antimalarial 7,20-diisocyanoadociane is presented. The
unexpected formation of undesired diastereomers in the key reaction
led to the structural reassignment of previous products of this type
of cascade and a reevaluation of the reversibility of the transannular
ring closure. During efforts to coax the reaction toward the desired
product, a transannular ene reaction provided tricyclic compounds
relevant to the kempane diterpenoids.
创建时间：
2014-09-05
