Selective Dilithiation of [Ti(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(η<sup>8</sup>-C<sub>8</sub>H<sub>8</sub>)] and Subsequent Conversion into Neutral and Cationic <i>ansa</i>-Complexes
收藏NIAID Data Ecosystem2026-03-07 收录
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Selective dimetalation of a sandwich complex featuring the cyclooctatetraene ligand has been accomplished for the first time. The isolation of the dilithiated species 1 subsequently enabled the isolation of a paramagnetic [2]stannatitanoarenophane (2) via salt elimination reaction. Chemical oxidation resulted in the formation of a rare example of a cationic ansa-complex (3).
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2016-02-23
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