Ferrocenyl-Passivated Nanoclusters: Synthesis of [Cu<sub>20</sub>Se<sub>6</sub>(Se<sub>2</sub>fc)<sub>4</sub>(PR<sub>2</sub>R‘)<sub>10</sub>] and [Cu<sub>40</sub>Se<sub>12</sub>(Se<sub>2</sub>fc)<sub>8</sub>(PPh<sub>3</sub>)<sub>9</sub>]
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The reagent Fe(η5-C5H4SeSiMe3)2 has been used for the formation of the new nanoclusters [Cu20Se6(Se2fc)4(PR2R‘)10] (R = Ph, R‘ = Et; R = R‘ = nBu) and [Cu40Se12(Se2fc)8(PPh3)9], which consist of ferrocenyl-passivated surfaces on CuSe cores.
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2016-05-06
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