Architectural Spiroligomers Designed for Binuclear Metal Complex Templating
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The first structurally, spectroscopically, and electronically characterized metal-spiroligomer complexes are reported. The binuclear [M2L2]4+ ions (M = Mn, Zn) are macrocyclic “squares” and are characterized by X-ray diffraction, 1H and 13C NMR, electronic absorption, emission, and mass spectroscopies. The manganese complex contains two spin-independent MnII ions and is additionally characterized using EPR and CD spectroscopies and CV.
创建时间：
2016-02-19
