N‑Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β‑Hydroxylation of Enals
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下载链接：
https://figshare.com/articles/dataset/N_Heterocyclic_Carbene_Catalyzed_Radical_Reactions_for_Highly_Enantioselective_Hydroxylation_of_Enals/2192680
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资源简介：
An
N-heterocyclic carbene-catalyzed β-hydroxylation of enals
is developed. The reaction goes through a pathway involving multiple
radical intermediates, as supported by experimental observations.
This oxidative single-electron-transfer reaction allows for highly
enantioselective access to β-hydroxyl esters that are widely
found in natural products and bioactive molecules.
创建时间：
2016-02-14
