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Practical Synthesis and Diels−Alder Chemistry of [4]Dendralene

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https://figshare.com/articles/dataset/Practical_Synthesis_and_Diels_Alder_Chemistry_of_4_Dendralene/3373405
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Spectacular new atom efficient domino cycloaddition sequences involving [4]dendralene, the simplest cross-conjugated tetraene, are reported. Up to eight stereocenters, three new rings, and six C−C bonds are generated in one synthetic operation. The site selectivity of dienophile addition to cross-conjugated trienes and tetraenes is controlled with a simple Lewis acid.
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2016-05-12
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