Synthesis and Catalytic Activity of [Cp′Co(COD)] Complexes Bearing Pendant N‑Containing Groups
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https://figshare.com/articles/dataset/Synthesis_and_Catalytic_Activity_of_Cp_Co_COD_Complexes_Bearing_Pendant_N_Containing_Groups/2407378
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资源简介：
The novel Co(I)-complex [CpCNCo(COD)] (CpCN = η5-(C5H4CMe2CH2CN), COD = 1,5-cyclooctadiene; 3) with
a substituted cyclopentadienyl ligand containing a pendant nitrile
moiety has been synthesized and characterized by X-ray diffraction.
The reactivity of the nitrile group in 3 has been investigated
regarding its behavior in cyclization reactions with alkynes, leading
to three new complexes containing pendant 2-pyridyl groups. All synthesized
complexes have been evaluated as catalysts in the [2 + 2 + 2] cycloaddition
reaction of 1,6-heptadiyne and benzonitrile.
创建时间：
2016-02-19
