Heterochiral Triangulo Nickel Complex as Evidence of a Large Positive Nonlinear Effect in Catalysis
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https://figshare.com/articles/dataset/Heterochiral_Triangulo_Nickel_Complex_as_Evidence_of_a_Large_Positive_Nonlinear_Effect_in_Catalysis/2959681
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资源简介：
A novel triangulo complex was generated by heating, in vacuo, a
racemic C2-symmetric octahedral nickel(II) diamine complex. The
trinuclear species was identified by single-crystal X-ray diffraction,
which revealed a 2:1 ligand stereochemistry relationship in each
unit. This solid-state structure evidences the hypothesis that a 1:2
stereochemical relationship lies at the heart of the strong positive
nonlinear effect observed in enecarbamate aldol-like reactions
catalyzed by nickel(II) diamine complexes.
创建时间：
2016-06-03
