Chiral Induction via the Disassembly of Diruthenium(II,III) Tetraacetate by Chiral Diphosphines
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https://figshare.com/articles/dataset/Chiral_Induction_via_the_Disassembly_of_Diruthenium_II_III_Tetraacetate_by_Chiral_Diphosphines/2575681
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资源简介：
[Ru2(μ-O2CCH3)4(MeOH)2](PF6) reacts with chiral diphosphines
(R,R)- and (S,S)-chiraphos, leading to disassembly and production of the
enantiomers Λ-[Ru(η2-O2CCH3)(η2-(R,R)-chiraphos)2](PF6) and Δ-[Ru(η2-O2CCH3)(η2-(S,S)-chiraphos)2](PF6) in high yield
and purity. X-ray crystallography and solid-state circular dichroism
(CD) show that only the indicated isomers are present in the solid
state. Solution CD measurements also indicate their predominance in
solution.
创建时间：
2011-12-05
