Versatile Behavior of the Schiff Base Ligand 2,5-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>C(H)N(2,4,6-Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub>) toward Cyclometalation Reactions: C(sp<sup>2</sup>,phenyl)−H vs C(sp<sup>3</sup>,methyl)−H Activation
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Treatment of the Schiff base ligand a with palladium(II) acetate in toluene gave 1a, with metalation of an aromatic phenyl carbon atom. Reaction at room temperature gave the trinuclear complex 4a. Treatment of a with palladium(II) acetate in refluxing acetic acid gave 1a′. The reaction of complexes 1a and 1a′ with sodium chloride or lithium bromide gave the halogen-bridged complexes 2a, 3a, 2a′, and 3a′.
创建时间：
2010-08-09
