Diastereoselective Conjugate Addition of Organocuprates to Chiral <i>N</i>-Enoyl Oxazolidinethiones
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
Addition of organocuprates, generated in situ using an excess of a 1:2 mixture of CuI·DMS and Grignard reagent, to N-enoyl oxazolidinethiones in the presence of excess TMSI gave preferentially the anti diastereomer where the addition took place when the conformation of the substrate was syn-s-cis. The reaction was investigated with indene-based and three different phenyl glycine derived oxazolidinethiones.
创建时间：
2010-10-01
