Rhodium(II)-Catalyzed Asymmetric Sulfur(VI) Reduction of Diazo Sulfonylamidines
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https://figshare.com/articles/dataset/Rhodium_II_Catalyzed_Asymmetric_Sulfur_VI_Reduction_of_Diazo_Sulfonylamidines/2551789
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资源简介：
Diazo sulfonylamidines readily undergo enantioselective
oxygen
transfer from sulfur to carbon atom in the presence of chiral rhodium(II)
carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric
atom transfer “reduction” occurs rapidly under mild
conditions, and sulfinylamidines are obtained in excellent yield.
创建时间：
2016-02-22
