Palladium-Catalyzed Diacetoxylation of Methylenecyclopropanes via C(sp<sup>3</sup>)−C(sp<sup>3</sup>) Bond Breaking
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
Methylenecyclopropanes 1 can undergo an effective palladium-catalyzed ring-opening reaction to give the diacetoxylated products 2 in good yields through C−C bond cleavage in the presence of Pd(OAc)2 using PhI(OAc)2 as the terminal oxidant and Bu4NI as an additive under mild conditions. A plausible reaction mechanism has been also discussed on the basis of experimental results.
创建时间：
2016-02-25
