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Linear Bis(perfluoroalkyl) Complexes of Nickel Bipyridine

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https://figshare.com/articles/dataset/Linear_Bis_perfluoroalkyl_Complexes_of_Nickel_Bipyridine/2547067
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Three new complexes were prepared: [(dtbpy)­Ni­(CF3)2] (1), [(dtbpy)­Ni­(CF2CF3)2] (2), and [(dtbpy)­Ni­(CH3)2] (3) (dtbpy = 4,4′-di-tert-butyl-2,2′-bipyridine). Remarkable differences in the structure, electronics, reactivity, and absorption of visible light for the alkyl versus perfluoroalkyl complexes were observed and are detailed in this report.
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2012-02-27
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