Double-Sandwich Pentalene Complexes M2(pent†)2 (M = Rh, Pd; pent† = 1,4-Bis(triisopropylsilyl)pentalene): Synthesis, Structure, and Bonding
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The bis(pentalene) complexes M2(pent†)2 (M = Rh (1), Pd (2); pent† = 1,4-bis(triisopropylsilyl)pentalene) have been synthesized and structurally characterized. In both 1 and 2 the metals have a formal electron count in excess of 18 per metal center, and DFT calculations indicate antibonding metal–metal interactions are present in 1, whereas 2 involves antibonding metal–ligand interactions.
创建时间：
2016-02-20
