Metal-Free Direct α‑Selective Arylation of Boron Dipyrromethenes via Base-Mediated C–H Functionalization
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https://figshare.com/articles/dataset/Metal_Free_Direct_Selective_Arylation_of_Boron_Dipyrromethenes_via_Base_Mediated_C_H_Functionalization/2075878
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A metal-free direct α-selective arylation of BODIPYs has been developed based on base-mediated C–H functionalization with easily accessible diaryliodonium salts, which provides a straightforward facile access to a variety of α-arylBODIPY dyes. The α-regioselectivity was confirmed by X-ray analysis, and was studied by DFT calculation. The resultant dyes show strong absorption and emission over a broad range of spectra tunable via the simple variation of the diaryliodonium salts.
创建时间：
2016-02-12
