Complex Annulations through Silver Carbenoid Intermediate: An Alternative Entry to Transformations of 1,2,3-Triazoles
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https://figshare.com/articles/dataset/Complex_Annulations_through_Silver_Carbenoid_Intermediate_An_Alternative_Entry_to_Transformations_of_1_2_3-Triazoles/5216182
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资源简介：
An
alternative entry to transformations of N-sulfonyl-4-(2-(ethynyl)aryl)-1,2,3-triazoles
with various generated in situ or external nucleophiles by means of
silver catalysis for producing diverse functionalized isoquinolines
is described. Mechanistically, the reaction is proposed to involve
a key silver carbenoid intermediate, thus enabling the formation of
multiple chemical bonds via ring opening, N2 extrusion,
silver carbenoid formation, nucleophilic addition, and complex annulations
cascades.
创建时间：
2017-07-17
