Synthesis of Fused Carbocycles via a Selective 6-Endo Dig Gold(I)-Catalyzed Carbocyclization
收藏Figshare2016-02-22 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_of_Fused_Carbocycles_via_a_Selective_6_i_Endo_i_Dig_Gold_I_Catalyzed_Carbocyclization/2597848
下载链接
链接失效反馈官方服务：
资源简介：
A gold-catalyzed synthesis of fused carbocycles via a regioselective 6-endo dig process is reported. The selectivity can be modulated by the steric and electronic properties of gold(I) complexes. The ligands can influence the pathway selectivity for the first bond formation rather than through a common intermediate generated after an initial bond formation. This gold(I)-catalyzed transformation provides access to synthetically useful carbocyclic motifs that are found in numerous diterpenoid natural products.
创建时间：
2016-02-22
