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Vanadocene-Mediated Ionization of Water in the Aqua Species [H<sub>2</sub>O·B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>]: Structural Characterization of the Hydride and Hydroxide Complexes [Cp<sub>2</sub>V(μ-H)B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>] and [Cp<sub>2</sub>V(μ-OH)B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>]

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NIAID Data Ecosystem2026-03-06 收录
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The reaction of Cp2V with B(C6F5)3 in the presence of water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1) and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both of which have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of water in the presence of B(C6F5)3.

创建时间:
2016-05-05
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