Lanthanide Template Synthesis of a Molecular Trefoil Knot
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https://figshare.com/articles/dataset/Lanthanide_Template_Synthesis_of_a_Molecular_Trefoil_Knot/2040720
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资源简介:
We
report on a complex featuring three 2,6-pyridinedicarboxamide
ligands entwined around a lanthanide (Ln3+) ion. The ligand
strands can be cyclized by ring-closing olefin metathesis to form
a molecular trefoil knot in 58% yield. Demetalation with tetraethylammonium
fluoride quantitatively generates the wholly organic 81-atom-loop
trefoil knot.
创建时间:
2015-12-17



